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New 10-membered inorganic heterocyclic diphosphanes, PhN(PX)(2)[(-OC(6)H(2)((T)Bu)(2))(mu-S)(((t)Bu)(2)C(6)H(2)O-)] (x = cl, f). Synthesis and transition metal complexes (molybdenum(0), ruthenium(II), palladium(II), and platinum(II)) of heterocyclic diphosphanes. crystal and molecular structures of the chloro derivative, PhN(PCl)(2)[(-OC(6)H(2)((t)Bu)(2))(mu-S)(((t)Bu)(2)C(6)H(2)O-)], and of a molybdenum(0) complex of the fluoro derivative, [Mo(CO)(3)[eta(3)-PhN(PF)(2)[(-OC(6)H(2)((t)Bu)(2))(mu-S)(((t)Bu)(2)C(6)H(2)O-)]-kappa P,kappa P,kappa S]]. [electronic resource] by Producer: 20020104
In:
Inorganic chemistry vol. 40
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