Hay, Daniel N T <br/><br/>
Gallium and gallium dichloride, new solid-state reductants in preparative transition metal chemistry. New, lower temperature syntheses and convenient isolation of hexatantalum tetradecachloride octahydrate, Ta(6)(mu-Cl)(12)Cl(2)(OH(2))(4).4H(2)O, and synthesis and solid-state structure of a tetraalkylammonium derivative, [N(CH(2)Ph)Bu(3)](4)[Ta(6)(mu-Cl)(12)Cl(6)], of the reduced [Ta(6)(mu-Cl)(12)](2+) cluster core(1).  [electronic resource] 

 -  Inorganic chemistry  Sep 2002 
 - 4700-7 p.  digital 
<br/><br/> Publication Type: Journal Article; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, Non-P.H.S.; Research Support, U.S. Gov't, P.H.S. 
<br/><br/><label>ISSN: </label>0020-1669 
<br/><br/><label>Standard No.: </label>10.1021/ic0201452  doi 
<br/><br/><label>Subjects--Topical Terms: </label><br/>Chemistry, Inorganic--methods<br/>Chlorides--chemistry<br/>Crystallography, X-Ray<br/>Gallium--chemistry<br/>Molecular Conformation<br/>Organometallic Compounds--chemical synthesis<br/>Tantalum--chemistry