TY - GEN AU - Bianciotto,Marc AU - Barthelat,Jean-Claude AU - Vigroux,Alain TI - Reactivity of phosphate monoester monoanions in aqueous solution. 1. Quantum mechanical calculations support the existence of "anionic zwitterion" MeO(+)(H)PO(3)(2-) as a key intermediate in the dissociative hydrolysis of the methyl phosphate anion SN - 0002-7863 PY - 2002///0819 KW - Anions KW - chemistry KW - Hydrolysis KW - Kinetics KW - Methanol KW - Organophosphates KW - Quantum Theory KW - Thermodynamics KW - Water N1 - Publication Type: Journal Article; Research Support, Non-U.S. Gov't UR - https://doi.org/10.1021/ja0200948 ER -