Bianciotto, Marc

Reactivity of phosphate monoester monoanions in aqueous solution. 1. Quantum mechanical calculations support the existence of "anionic zwitterion" MeO(+)(H)PO(3)(2-) as a key intermediate in the dissociative hydrolysis of the methyl phosphate anion. [electronic resource] - Journal of the American Chemical Society Jun 2002 - 7573-87 p. digital

Publication Type: Journal Article; Research Support, Non-U.S. Gov't

0002-7863

10.1021/ja0200948 doi


Anions--chemistry
Hydrolysis
Kinetics
Methanol--chemistry
Organophosphates--chemistry
Quantum Theory
Thermodynamics
Water--chemistry