Reactivity of phosphate monoester monoanions in aqueous solution. 1. Quantum mechanical calculations support the existence of "anionic zwitterion" MeO(+)(H)PO(3)(2-) as a key intermediate in the dissociative hydrolysis of the methyl phosphate anion. [electronic resource]
- Journal of the American Chemical Society Jun 2002
- 7573-87 p. digital
Publication Type: Journal Article; Research Support, Non-U.S. Gov't
0002-7863
10.1021/ja0200948 doi
Anions--chemistry Hydrolysis Kinetics Methanol--chemistry Organophosphates--chemistry Quantum Theory Thermodynamics Water--chemistry