Synthesis, structure, and reactions of chiral rhenium vinylidene and acetylide complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(X)]n+. Vinylidene complexes that are formed by stereospecific C.beta. electrophilic attack, exist as two Re=C=C geometric isomers, and undergo stereospecific C.alpha. nucleophilic attack. [electronic resource]

By: Contributor(s): Producer: 20121002Description: 6096-109 p. digitalISSN:
  • 0002-7863
Online resources: In: Journal of the American Chemical Society vol. 110
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Publication Type: Journal Article

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