Reductive Elimination of H2 Activates Nitrogenase to Reduce the N≡N Triple Bond: Characterization of the E4(4H) Janus Intermediate in Wild-Type Enzyme.

Lukoyanov, Dmitriy

Reductive Elimination of H2 Activates Nitrogenase to Reduce the N≡N Triple Bond: Characterization of the E4(4H) Janus Intermediate in Wild-Type Enzyme. [electronic resource] - Journal of the American Chemical Society 08 2016 - 10674-83 p. digital

Publication Type: Journal Article; Research Support, N.I.H., Extramural; Research Support, U.S. Gov't, Non-P.H.S.

1520-5126

10.1021/jacs.6b06362 doi


Hydrogen--metabolism
Kinetics
Models, Molecular
Nitrogen--metabolism
Nitrogenase--chemistry
Oxidation-Reduction
Protein Conformation