SmI2-mediated radical cross-couplings of α-hydroxylated aza-hemiacetals and N,S-acetals with α,β-unsaturated compounds: asymmetric synthesis of (+)-hyacinthacine A2, (-)-uniflorine A, and (+)-7-epi-casuarine.

Liu, Xue-Kui

SmI2-mediated radical cross-couplings of α-hydroxylated aza-hemiacetals and N,S-acetals with α,β-unsaturated compounds: asymmetric synthesis of (+)-hyacinthacine A2, (-)-uniflorine A, and (+)-7-epi-casuarine. [electronic resource] - The Journal of organic chemistry Jun 2011 - 4952-63 p. digital

Publication Type: Journal Article; Research Support, Non-U.S. Gov't

1520-6904

10.1021/jo200600n doi


Acetals--chemistry
Alkaloids--chemical synthesis
Aza Compounds--chemistry
Free Radicals--chemistry
Hydroxylation
Indolizines--chemical synthesis
Iodides--chemistry
Molecular Structure
Pyrroles--chemical synthesis
Pyrrolizidine Alkaloids--chemical synthesis
Samarium--chemistry
Stereoisomerism