Solvent dependence of the kinetic isotope effect in the reaction of ascorbate with the 2,2,6,6-tetramethylpiperidine-1-oxyl radical: tunnelling in a small molecule reaction.

Sajenko, Ivana

Solvent dependence of the kinetic isotope effect in the reaction of ascorbate with the 2,2,6,6-tetramethylpiperidine-1-oxyl radical: tunnelling in a small molecule reaction. [electronic resource] - The journal of physical chemistry. A Mar 2010 - 3423-30 p. digital

Publication Type: Journal Article; Research Support, Non-U.S. Gov't

1520-5215

10.1021/jp911086n doi


Ascorbic Acid--chemistry
Cyclic N-Oxides--chemistry
Deuterium--chemistry
Dioxanes--chemistry
Isotopes
Kinetics
Solvents--chemistry
Temperature
Thermodynamics
Water--chemistry