Gallium and gallium dichloride, new solid-state reductants in preparative transition metal chemistry. New, lower temperature syntheses and convenient isolation of hexatantalum tetradecachloride octahydrate, Ta(6)(mu-Cl)(12)Cl(2)(OH(2))(4).4H(2)O, and synthesis and solid-state structure of a tetraalkylammonium derivative, [N(CH(2)Ph)Bu(3)](4)[Ta(6)(mu-Cl)(12)Cl(6)], of the reduced [Ta(6)(mu-Cl)(12)](2+) cluster core(1).

Hay, Daniel N T

Gallium and gallium dichloride, new solid-state reductants in preparative transition metal chemistry. New, lower temperature syntheses and convenient isolation of hexatantalum tetradecachloride octahydrate, Ta(6)(mu-Cl)(12)Cl(2)(OH(2))(4).4H(2)O, and synthesis and solid-state structure of a tetraalkylammonium derivative, [N(CH(2)Ph)Bu(3)](4)[Ta(6)(mu-Cl)(12)Cl(6)], of the reduced [Ta(6)(mu-Cl)(12)](2+) cluster core(1). [electronic resource] - Inorganic chemistry Sep 2002 - 4700-7 p. digital

Publication Type: Journal Article; Research Support, Non-U.S. Gov't; Research Support, U.S. Gov't, Non-P.H.S.; Research Support, U.S. Gov't, P.H.S.

0020-1669

10.1021/ic0201452 doi


Chemistry, Inorganic--methods
Chlorides--chemistry
Crystallography, X-Ray
Gallium--chemistry
Molecular Conformation
Organometallic Compounds--chemical synthesis
Tantalum--chemistry