Total syntheses of (-)-methyl atis-16-en-19-oate, (-)-methyl kaur-16-en-19-oate, and (-)-methyl trachyloban-19-oate by a combination of palladium-catalyzed cycloalkenylation and homoallyl-homoallyl radical rearrangement.

Toyota, M

Total syntheses of (-)-methyl atis-16-en-19-oate, (-)-methyl kaur-16-en-19-oate, and (-)-methyl trachyloban-19-oate by a combination of palladium-catalyzed cycloalkenylation and homoallyl-homoallyl radical rearrangement. [electronic resource] - The Journal of organic chemistry Jul 2000 - 4565-70 p. digital

Publication Type: Journal Article

0022-3263

10.1021/jo000142b doi


Alkaloids--chemical synthesis
Catalysis
Cyclization
Diterpenes--chemical synthesis
Palladium--chemistry
Polycyclic Compounds--chemical synthesis
Stereoisomerism